Ok, I'm going to take a go at this and try to keep it realistic and not just put every song down... I think limiting to 12-15 songs is fair for a main headline tour. So:
Rise With Me
Adrenalize
You're Gonna' Listen
Lost At Sea
The Promise
Next Life
Standing Alone
World In Flames (acoustic with Maria on piano)
Scarlet
Wh*re
Her Kiss
Iron Army
The Gun Show
Blood
--ENCORE--
Prayers